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<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">One other note we ran up against in Princeton about 10-15 years ago: The Harvard lab (built perhaps 15-20 years ago) is below grade, but on one side the ground
was somewhat excavated to let some minimal daylight in, so you might claim it is not below grade. As a result, they were able to either store (maybe) or use (that I’m fairly sure about) silane in the lab. We were designing a new building in a tight
space, with some highly-paid consultants and architects who were supposedly experts on lab design and fire codes. They came up for us with something similar following the Harvard approach. After the design was done (and we had paid them), it turned
out we found out that the national code (IBC, IFC??) that had allowed the Harvard approach had changed (which our “experts” were not at all aware of), so their design (and all the time we sunk into it) was worthless, and we had to start over (with new consultants.)
I don’t recall the exact technical details about H use and B use (are those the right terms?) but that is the gist of the story. )#)$#&*$(#&#$(#*(#&@!!
<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">So Beware (and be safe)<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">Jim Sturm<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D">********************************************</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D">Prof. James C. Sturm</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D"> Stephen R. Forrest Professor in Electrical Engineering</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D"> Princeton University</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D"> B410 E-Quad, Olden St.</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D"> Princeton, NJ 08540</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D"> 609-258-5610, fax: 609-258-1177</span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:#1F497D">
<a href="mailto:sturm@princeton.edu" title="mailto:sturm@princeton.edu">sturm@princeton.edu</a></span><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
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<p class="MsoNormal"><b><span style="font-size:11.0pt;font-family:"Calibri",sans-serif">From:</span></b><span style="font-size:11.0pt;font-family:"Calibri",sans-serif"> labnetwork-bounces@mtl.mit.edu [mailto:labnetwork-bounces@mtl.mit.edu]
<b>On Behalf Of </b>Paul, Jack<br>
<b>Sent:</b> Thursday, December 07, 2017 8:37 PM<br>
<b>To:</b> Michael Hume <michael.hume@ualberta.ca>; labnetwork@mtl.mit.edu<br>
<b>Subject:</b> Re: [labnetwork] Silane Installation below grade<o:p></o:p></span></p>
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<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal"><a name="_MailEndCompose"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">Michael,</span></a><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">The building and fire codes in your jurisdiction (Edmonton) are probably different than the International Building and Fire Codes, but the general approach of
those codes (IBC and IFC) is to restrict hazardous materials in basements because a) it is extremely difficult to fight fires at basement level, and b) basements are harder to exit, and c) typically basements cannot have explosion venting (as John Schott noted
they had at Stanford).<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">As a pyrophoric gas, silane deflagrates extremely fast – almost fast enough to be officially labeled an “explosion” and thus when it is stored indoors it is often
required to have an explosion vent (this is the lightly fastened roof structure that John mentioned in his email).<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">The IBC and IFC restrict the quantity of any pyrophoric material allowable in a single control area (i.e. one floor, or one fire-wall isolated area of a floor)
to maximum of 4 lbs or 50 cu ft in storage, and 10 cu ft in “use-closed system”. As I noted, your jurisdiction in Canada probably has not adopted the IBC and IFC, but my guess is that whatever code applies in your municipality, it will have similar restrictions.
Additionally, it may also refer to CGA G13 (as does the IFC) for design requirements for silane systems, thus adopting CGA-13 by reference.<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D">In short – you may be violating building and fire code restrictions by placing the silane in the basement level. Your campus architect or fire marshal should
be able to provide guidance, or alternatively a friendly architect or lab planner.<o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><span style="font-size:7.5pt;font-family:"Arial Black",sans-serif;color:#C60C30">Jack Paul,</span><span style="font-size:9.0pt;font-family:"Arial Black",sans-serif;color:#C60C30">
</span><span style="font-size:7.5pt;font-family:"Arial",sans-serif;color:#56585A">RA, LEED AP BD+C</span><span style="font-size:9.0pt;font-family:"Arial Black",sans-serif;color:#C60C30"><o:p></o:p></span></p>
<p class="MsoNormal" style="margin-bottom:12.0pt"><b><span style="font-size:8.5pt;font-family:"Arial",sans-serif;color:#C60C30">D</span></b><span style="font-size:8.5pt;font-family:"Arial",sans-serif;color:#56585A"> 602.474.3940
</span><b><span style="font-size:8.5pt;font-family:"Arial",sans-serif;color:#C60C30">M</span></b><span style="font-size:8.5pt;font-family:"Arial",sans-serif;color:#56585A"> 602.369.2086<o:p></o:p></span></p>
<p class="MsoNormal"><a href="http://hdrinc.com/follow-us"><span style="font-size:8.5pt;font-family:"Arial",sans-serif;color:#595959;text-decoration:none">hdrinc.com/follow-us</span></a><span style="font-size:8.5pt;font-family:"Calibri",sans-serif;color:#595959"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:11.0pt;font-family:"Calibri",sans-serif;color:#1F497D"><o:p> </o:p></span></p>
<p class="MsoNormal"><b><span style="font-size:11.0pt;font-family:"Calibri",sans-serif">From:</span></b><span style="font-size:11.0pt;font-family:"Calibri",sans-serif">
<a href="mailto:labnetwork-bounces@mtl.mit.edu">labnetwork-bounces@mtl.mit.edu</a> [<a href="mailto:labnetwork-bounces@mtl.mit.edu">mailto:labnetwork-bounces@mtl.mit.edu</a>]
<b>On Behalf Of </b>Michael Hume<br>
<b>Sent:</b> Thursday, December 7, 2017 11:05 AM<br>
<b>To:</b> <a href="mailto:labnetwork@mtl.mit.edu">labnetwork@mtl.mit.edu</a><br>
<b>Subject:</b> [labnetwork] Silane Installation below grade<o:p></o:p></span></p>
<p class="MsoNormal"><o:p> </o:p></p>
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<p class="MsoNormal">Hello Colleagues, <o:p></o:p></p>
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<p class="MsoNormal"><o:p> </o:p></p>
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<p class="MsoNormal">We are in the process if installing a new PECVD system which will use 100% SiH4. In reviewing CGA-G13, it states:<o:p></o:p></p>
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<b><span style="font-size:9.5pt">7.2 Indoor storage and use<br>
</span></b><span style="font-size:9.5pt">Buildings, rooms, or areas used for silane storage shall be constructed in accordance with the requirements of the local AHJ. <b>Silane shall not be stored in locations below grade</b> and silane bulk sources shall not
be located indoors. For transfilling exceptions, see Section 18.</span><o:p></o:p></p>
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<p class="MsoNormal"><o:p> </o:p></p>
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<p class="MsoNormal">In our case, an installation below grade may be preferred. I am wondering if anyone can provide any insight into the reasoning behind this. Does anybody store/use Silane below grade?<o:p></o:p></p>
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<p class="MsoNormal"><o:p> </o:p></p>
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<p class="MsoNormal">Thank-you,<o:p></o:p></p>
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<p class="MsoNormal">-Mike.<o:p></o:p></p>
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<p class="MsoNormal"> <o:p></o:p></p>
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<p class="MsoNormal">-- <o:p></o:p></p>
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<p style="margin:0in;margin-bottom:.0001pt"><b><u><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">PLEASE NOTE MY PHONE NUMBER HAS CHANGED:</span></u></b><b><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">
</span></b><b><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:red">780-953-5081</span></b><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt"><o:p> </o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">Michael Hume</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">Operations Manager</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">University of Alberta - nanoFAB</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">W1-060 ECERF Building</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">9107 - 116 Street</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">Edmonton, Alberta</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p style="margin:0in;margin-bottom:.0001pt"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black">Canada T6G 2V4
</span><span style="font-size:10.0pt"><o:p></o:p></span></p>
<p class="MsoNormal"><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:black"><a href="http://www.nanofab.ualberta.ca/" target="_blank"><span style="color:#1155CC">www.nanofab.ualberta.ca</span></a> Ph:
</span><b><span style="font-size:10.0pt;font-family:"Arial",sans-serif;color:red">780-953-5081* (New)</span></b><o:p></o:p></p>
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