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<p class="MsoNormal">Hi Sandra, a few years ago we allowed Zn deposition in our “dirty” sputter tool without a heated platen. Consider the attached vapor pressure v Temp chart – at the temps seen in our tool the vapor pressure is below the system base pressure.
Since that time we’ve noted no significant changes in base pressure and other users haven’t complained about their films being lower quality.
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<p class="MsoNormal">Please take this with a grain of salt – Zn dep is not very common here, just a few times per year. In addition, our users are not fabricating CMOS devices, almost all are biomed focused these days<o:p></o:p></p>
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<p class="MsoNormal">jim<o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in"><b>From:</b> labnetwork <labnetwork-bounces@mtl.mit.edu>
<b>On Behalf Of </b>Malhotra, Sandra Guy<br>
<b>Sent:</b> Monday, January 30, 2023 4:40 PM<br>
<b>To:</b> Fab Network <labnetwork@mtl.mit.edu><br>
<b>Subject:</b> [External] [labnetwork] Question about DC sputtering of zinc<o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span style="font-size:12.0pt;color:black">Howdy All from AggieFab,<o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span style="font-size:12.0pt;color:black">We have a user who requested permission to sputter zinc in our shared Lesker PVD75 DC sputtering tool. On the Lesker website, there is the following note:<o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span class="contentpasted0"><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white">"This material has a relatively </span></span><strong><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white">high
vapor pressure at low temperatures</span></strong><span class="contentpasted0"><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white"> which can cause ppm level contamination in the chamber and subsequent films. Careful
consideration should be taken before this material is used in any deposition system. For this reason, some users prefer to use only dedicated vacuum chambers for deposition."</span></span><span style="font-size:12.0pt;color:black"><o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span class="contentpasted0"><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white">I'd like to ask the group if they allow zinc depositions in their shared
tools if they follow it by a thorough paste with another material, like Ti? Or if this material is prohibited because it is problematic. </span></span><span style="font-size:12.0pt;color:black"><o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span class="contentpasted0"><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white">Thanks in advance for any inputs you may have.</span></span><span style="font-size:12.0pt;color:black"><o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in;background:white"><span class="contentpasted0"><span style="font-size:12.0pt;font-family:"Arial",sans-serif;color:#212529;background:white">Best,</span></span><span style="font-size:12.0pt;color:black"><o:p></o:p></span></p>
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<p class="MsoNormal" style="margin-left:.5in"><b>Sandra G. Malhotra, Ph.D. </b>| Technical Lab Manager
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<p class="MsoNormal" style="margin-left:.5in">AggieFab Nanofabrication Facility<o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in"><a href="https://aggiefab.tamu.edu/" title="https://aggiefab.tamu.edu/">https://aggiefab.tamu.edu/</a><o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in">Department of Electrical & Computer Engineering, College of Engineering | Texas A&M University<o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in">3253 TAMU | College Station, TX 77843<o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in">ph: 979.845.3199 | <a href="mailto:sandra.malhotra@tamu.edu">sandra.malhotra@tamu.edu</a><o:p></o:p></p>
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<p class="MsoNormal" style="margin-left:.5in"><span style="color:#861106">TEXAS A&M UNIVERSITY | FEARLESS on Every Front</span><o:p></o:p></p>
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